Pre-requisites: PHY-106, 203, 204, 301

PART A

1. Classical Statistical Mechanics

  • The scope of statistical physics
  • Assemblies
  • Phase Space and Phase Trajectory
  • Volume in Phase Space
  • Specification of States of a System
  • Density of States and its General Behavior
  • Liouville's theorem and its Consequences
  • The Postulates of Classical Statistical Mechanics
  • Stirling Approximation
  • Thermodynamic Probability
  • Statistical Equilibrium
  • Macrostates and Microstates

2. Statistics and Thermodynamics

  • Statistical concept of Temperature
  • Ensembles: Microcanonical Ensemble, Canonical Ensemble- its Connection with thermodynamic parameters and grandcanonical ensemble
  • Entropy
  • Free energy and other thermodynamic functions and their equilibrium conditions
  • Statistical Distribution Function
  • The Boltzmann partition function
  • Maxwell velocity distribution and mean values
  • Maxwell-Boltzmann Statistics and its Applications
  • Ideal monatomic gas
  • Harmonic oscillator
  • Specific heat of solids.

3. Quantum Statistical Mechanics

  • Postulates of Quantum Statistical Mechanics
  • Transition from Classical to Quantum Statistical Mechanics
  • Particle Statistics: Principle of indistinguishability for quantum particles, Spin-statistics connection, Exchange degeneracy
  • Average value and Quantum Statistics
  • The Density Matrix
  • Statistics of various Ensembles

PART B

4. Ferni Systems

  • Fermi-Dirac distribution function
  • Fermi-Dirac gas
  • Fermi Energy
  • Fermi Temperature
  • Fermi Velocity and Mean Velocity of a free electron in Metal
  • Degenerate Fermi systems
  • Landau Diamagnetism
  • Pauli Paramagnetism
  • Thermionic Emission
  • Statistical equilibrium in White Dwarfs

5. Bose Systems

  • Bose-Einstein distribution function and it's application
  • Planck’s radiation law
  • The Photon Gas
  • The Specific heat of Solids
  • The Phonon gas
  • Bose-Einstein Condensation
  • Superfluidity in Liquid He
  • Thermodynamics of Bose systems
  • Thermodynamic Properties of Diatomic Molecules
  • Nuclear Spin Effects in Diatomic Molecules.

6. The Condensed State

  • Solids at low and high temperature
  • Debye’s interpolation formula
  • Thermal expansion of solids
  • Quantum liquids with Bose-type spectrum
  • Quantum liquids with Fermi-type spectrum
  • The electronic spectra of metals
  • The electronic spectra of solid dielectrics.

7. Transport Phenomena and Phase Transition

  • Boltzmann transport equation
  • HH- theorem, validity of the equation
  • Mean free path, Viscosity and Diffusion
  • Electrical Conductivity, Brownian motion
  • Thermodynamic classification of Phase transition
  • Difference between first and second order phase transition
  • Mean-field theory
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