PHY-304 Statistical Mechanics
Pre-requisites: PHY-106, 203, 204, 301
PART A
1. Classical Statistical Mechanics
- The scope of statistical physics
- Assemblies
- Phase Space and Phase Trajectory
- Volume in Phase Space
- Specification of States of a System
- Density of States and its General Behavior
- Liouville's theorem and its Consequences
- The Postulates of Classical Statistical Mechanics
- Stirling Approximation
- Thermodynamic Probability
- Statistical Equilibrium
- Macrostates and Microstates
2. Statistics and Thermodynamics
- Statistical concept of Temperature
- Ensembles: Microcanonical Ensemble, Canonical Ensemble- its Connection with thermodynamic parameters and grandcanonical ensemble
- Entropy
- Free energy and other thermodynamic functions and their equilibrium conditions
- Statistical Distribution Function
- The Boltzmann partition function
- Maxwell velocity distribution and mean values
- Maxwell-Boltzmann Statistics and its Applications
- Ideal monatomic gas
- Harmonic oscillator
- Specific heat of solids.
3. Quantum Statistical Mechanics
- Postulates of Quantum Statistical Mechanics
- Transition from Classical to Quantum Statistical Mechanics
- Particle Statistics: Principle of indistinguishability for quantum particles, Spin-statistics connection, Exchange degeneracy
- Average value and Quantum Statistics
- The Density Matrix
- Statistics of various Ensembles
PART B
4. Ferni Systems
- Fermi-Dirac distribution function
- Fermi-Dirac gas
- Fermi Energy
- Fermi Temperature
- Fermi Velocity and Mean Velocity of a free electron in Metal
- Degenerate Fermi systems
- Landau Diamagnetism
- Pauli Paramagnetism
- Thermionic Emission
- Statistical equilibrium in White Dwarfs
5. Bose Systems
- Bose-Einstein distribution function and it's application
- Planck’s radiation law
- The Photon Gas
- The Specific heat of Solids
- The Phonon gas
- Bose-Einstein Condensation
- Superfluidity in Liquid He
- Thermodynamics of Bose systems
- Thermodynamic Properties of Diatomic Molecules
- Nuclear Spin Effects in Diatomic Molecules.
6. The Condensed State
- Solids at low and high temperature
- Debye’s interpolation formula
- Thermal expansion of solids
- Quantum liquids with Bose-type spectrum
- Quantum liquids with Fermi-type spectrum
- The electronic spectra of metals
- The electronic spectra of solid dielectrics.
7. Transport Phenomena and Phase Transition
- Boltzmann transport equation
- - theorem, validity of the equation
- Mean free path, Viscosity and Diffusion
- Electrical Conductivity, Brownian motion
- Thermodynamic classification of Phase transition
- Difference between first and second order phase transition
- Mean-field theory